COMPLEXES OF PYRIMIDINE-2-ONE WITH SOME 1ST TRANSITION SERIES METAL-IONS

被引：22

作者：

GOODGAME, DML

JEEVES, I

机构：

[1] Chemistry Department, Imperial College of Science andTechnology, London

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)91654-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations and spectral properties are reported of complexes of pyrimidine-2-one (Hpymo) with metal ions of the series Mn-Zn, and also Cd. The results show that the exocyclic oxygen atom in Hpymo has much less tendency to bind to these metal ions than does the sulphur atom in pyrimidine. 2-thione. With cobalt(ll) Hpymo readily forms tetrahedral[Co(Hpymo)4]2+ ions in which Hpymo binds through the non-protonated ring nitrogen. Such cations are present in: [Co(Hpymo)4]X2.Hpymo (X = I or CIO4), [Co(Hpymo)4] [CoCl4], and [Co- (Hpymo)4X2 (X = Cl or Br). © 1979.

引用

页码：157 / 162

页数：6

共 22 条

[1] COMPLEXES OF PYRIMIDINE-2-THIONE WITH SOME BIVALENT-METAL HALIDES OF 1ST TRANSITION SERIES [J].

ABBOT, J ;

GOODGAME, DML ;

JEEVES, I .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (07) :880-884

[2]

[Anonymous], PROG INORG CHEM

[3]

CARRABINE JA, 1971, BIOCHEMISTRY-US, V10, P292

[4] INTERACTION OF METAL-IONS WITH PYRIMIDINE-DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF TETRAKIS(2-PYRIMIDINONE)COPPER(II) PERCHLORATE-ETHANOL [J].

CARTWRIGHT, BA ;

REYNOLDS, CD ;

SKAPSKI, AC .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JUN15) :1883-1887

[5] ELECTRONIC STRUCTURES OF TETRAHEDRAL COBALT(II) COMPLEXES [J].

COTTON, FA ;

GOODGAME, M ;

GOODGAME, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (23) :4690-&

[6]

Goldstein M., 1970, INORG CHEM ACTA, V4, P342

[7] ORBITAL SPLITTINGS OF SOME TETRAGONAL NICKEL(2) COMPLEXES WITH HETEROCYCLIC AMINE LIGANDS [J].

GOODGAME, DM ;

GOODGAME, M ;

HITCHMAN, MA ;

WEEKS, MJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (12) :1769-&

[8] SPECTRAL + MAGNETIC STUDIES OF SOME POLYMERIC COMPLEXES OF NICKEL HALIDES WITH HETEROCYCLIC LIGANDS [J].

GOODGAME, DM ;

GOODGAME, M ;

WEEKS, MJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC) :5194-&

[9] ELECTRONIC SPECTRA OF SOME 6-COORDINATE COMPLEXES OF IRON(2) WITH HETEROCYCLIC AMINES [J].

GOODGAME, DM ;

GOODGAME, M ;

HITCHMAN, MA ;

WEEKS, MJ .

INORGANIC CHEMISTRY, 1966, 5 (04) :635-&

[10] VERSATILITY OF COORDINATION BEHAVIOR OF 1-METHYLPYRIMIDINE-2-THIONE TOWARDS METAL-IONS OF 1ST TRANSITION SERIES [J].

GOODGAME, DML ;

LEACH, GA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (12) :1705-1709

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