POTASSIUM HYDROGENSULFATE DIHYDROGENSULFATE, K(HSO4)(H2SO4) SYNTHESIS AND CRYSTAL-STRUCTURE

被引：7
|
作者：
KEMNITZ, E
WERNER, C
WORZALA, H
TROJANOV, S
机构：
[1] INST ANGEW CHEM ADLERSHOF,D-12489 BERLIN,GERMANY
[2] MOSCOW MV LOMONOSOV STATE UNIV,FAC CHEM,MOSCOW 119899,RUSSIA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期
关键词：
POTASSIUM HYDROGENSULFATE DIHYDROGENSULFATE; SYNTHESIS; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19956210631
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals with the composition KH3(SO4)(2) have been synthesized from the system Potassium sulfate/sulfuric acid. The hitherto crystallographically not investigated compound crystallizes in the monoclinic space group P2(1)/c (14) with the unit cell parameters a = 7.654(3), b = 11.473(5) and c = 8.643(3) Angstrom, beta = 112.43(3)degrees, V = 701.6 Angstrom(3), Z = 4 and D-x = 2.22 g . cm(-3). The structure contains two types of tetrahedra, SO3(OH) and SO2(OH)(2)). These tetrahedra form tetramers via hydrogen bonds consisting of both, two SO3(OH) and two SO2(OH)(2) tetrahedra. The tetramers are linked to each other via hydrogen bonds. Potassium is coordinated by 9 oxygen atoms which belong to both kinds of tetrahedra. These potassium oxygen polyhedra are connected by common faces forming chains running parallel z.
引用
收藏
页码：1075 / 1079
页数：5
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