FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE STUDIES OF GAS-PHASE REACTIONS BETWEEN TUNGSTEN IONS AND HYDROCARBONS

被引：12

作者：

KIKHTENKO, AV ^{[1
]}

GONCHAROV, VB ^{[1
]}

MOMOT, KI ^{[1
]}

ZAMARAEV, KI ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,BORESKOV INST CATALYSIS,PROSPEKT AK LAVRENTIEVA 5,NOVOSIBIRSK 630090,RUSSIA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 06期

关键词：

D O I：

10.1021/om00018a060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

FT/ICR spectrometry has been used for gas-phase studies of the interaction between singly-charged positive tungsten ions and hydrocarbons (alkanes C2-C-9, alkenes C2-C6, and cycloalkanes C3-C6). It is shown that this interaction results mainly in dehydrogenation products. The number of H-2 molecules eliminated depends upon the size and type of hydrocarbon and varies from 1 to 6. Significant amounts of C-C cleavage products have been found in the cases of cyclopropane and 2-methylpropene only.

引用

页码：2536 / 2538

页数：3

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