MIXED-LIGAND COMPLEXES OF RUTHENIUM(II) WITH HETEROCYCLIC DITHIOCARBAMATES

被引：6
作者：
CHINNUSAMY, V
NATARAJAN, K
机构：
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1993年 / 23卷 / 05期
关键词：
D O I：
10.1080/15533179308016857
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Several new hexacoordinated ruthenium(II) complexes of the type [RuH(CO)(LL') PPh3)2] and [RuH(CO)(B)(LL')(PPh3)] (where LL' = Morpholine dithiocarbamate (Morph dtc) piperidine dithiocarbamate (Pip dtc) and piperazine dithiocarbamate (Pz dtc) B = pyridine(py), piperidine(pip), morpholine(morph) have been synthesised. in all these complexes the heterocyclic dithiocarbamates behave as a uninegative bidentate (SS-) chelating ligand. All the complexes have been characterised on the basis of their analytical and spectroscopic data.
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页码：745 / 756
页数：12
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