THE STUDY OF CATALYST EFFECTS ON THE COMPLEXATION OF ARENES WITH CR(CO)6 - AN OVERVIEW

被引：25

作者：

HUDECEK, M ^{[1
]}

GAJDA, V ^{[1
]}

TOMA, S ^{[1
]}

机构：

[1] COMENIUS UNIV BRATISLAVA,DEPT ORGAN CHEM,CS-84215 BRATISLAVA,SLOVAKIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80046-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New results from our thorough investigation of different catalystic effects on the rate and yields of complexation of arenes with Cr(CO) are presented with a short review of the subject. With decalin as solvent the following substances were found to be the best catalysts: butyl acetate, ethyl formate, and dimethyl succinate. Butyl acetate proved to be the catalyst also in di-n-butyl ether. Special attention was paid to the complexation of naphthalene, and chlorobenzene. Some unsuccessful attempts at asymmetric induction of complexation are also described.

引用

页码：155 / 160

页数：6

共 15 条

[1]

[Anonymous], 1979, INORG SYNTH

[2]

FISCHER EO, 1958, Z NATURFORSCH PT B, V13, P458

[3] UBER AROMATENKOMPLEXE VON METALLEN .24. UBER GEMISCHTE TRICARBONYLKOMPLEXE DES CHROMS, MOLYBDANS UND WOLFRAMS MIT BENZOL UND SEINEN DERIVATEN [J].

FISCHER, EO ;

OFELE, K ;

ESSLER, H ;

FROHLICH, W ;

MORTENSEN, JP ;

SEMMLINGER, W .

CHEMISCHE BERICHTE-RECUEIL, 1958, 91 (12) :2763-2772

[4] ACID-CATALYZED COMPLEXATION OF ARENES WITH CR(CO)6 [J].

HRNCIAR, P ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 413 (1-3) :161-164

[5]

HRNCIAR P, IN PRESS COLLECT CZE

[6] AN IMPROVED METHOD FOR THE SYNTHESIS OF ETA-6-ARENETRICARBONYLCHROMIUM COMPLEXES [J].

HUDECEK, M ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 393 (01) :115-118

[7] A SIMPLE ROUTE TO (ETA-6-ARENE)TRICARBONYLCHROMIUM COMPLEXES AND A SYSTEMATIC STUDY OF DIFFERENT CATALYSTS FOR COMPLEXATION OF ARENES WITH CR(CO)6 [J].

HUDECEK, M ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 406 (1-2) :147-151

[8] SYNTHESIS AND CHARACTERIZATION OF TRICARBONYLCHROMIUM COMPLEXES OF SUBSTITUTED BENZOIC-ACID ESTERS [J].

MAHAFFY, CAL ;

HAMILTON, J .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1987, 17 (01) :43-48

[9]

Natta G., 1958, CHIMICA IND, V40, P287

[10] THE ORGANIC CHEMISTRY OF THE TRANSITION ELEMENTS .1. TRICARBONYLCHROMIUM DERIVATIVES OF AROMATIC COMPOUNDS [J].

NICHOLLS, B ;

WHITING, MC .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (FEB) :551-556

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