OXIDATION OF 2-METHYLCYCLOHEXANONE AND CYCLOHEXANONE BY DIOXYGEN CATALYZED BY VANADIUM-CONTAINING HETEROPOLYANIONS

被引：58

作者：

ATLAMSANI, A

BREGEAULT, JM

ZIYAD, M

机构：

[1] UNIV PARIS 06,DEPT CHIM,CATALYSE & CHIM SURFACES LAB,CNRS,URA 1428,TOUR 54,BOITE 196,F-75252 PARIS 05,FRANCE

[2] UNIV MOHAMMED 5,FAC SCI,PHYSICOCHIM MAT & CATALYSE LAB,RABAT,MOROCCO

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 21期

关键词：

D O I：

10.1021/jo00073a026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Methylcyclohexanone is oxidized by dioxygen in the presence of H3+n[PMo12-nVnO40].aq to give 6-oxoheptanoic acid. Solvent effects are studied. The same precursors with cyclohexanone in aqueous acetic acid give adipic acid as the major product and other dicarboxylic acids by oxidation of 6-oxohexanoic acid.

引用

页码：5663 / 5665

页数：3

共 49 条

[1]

ATLAMSANI A, 1992, SYNTHESIS-STUTTGART, P79

[2] Oxidative cleavage of cyclic alpha-keto alcohols by means of lead tetraacetate II [J].

Baer, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :1416-1421

[3]

BREGEAULT JM, 1988, CR ACAD SCI II, V307, P2011

[4]

BREGEAULT JM, 1992, CATALYSE HOMOGENE CO

[5]

CANNERI G, 1926, GAZZ CHIM ITAL, V56, P871

[6] INDUSTRIAL-PRODUCTION AND USE OF ADIPIC ACID [J].

CASTELLAN, A ;

BART, JCJ ;

CAVALLARO, S .

CATALYSIS TODAY, 1991, 9 (03) :237-254

[7]

CLAUS RE, 1986, ORG SYNTH, V64, P150

[8]

COURTIN P, 1971, REV CHIM MINER, V8, P75

[9] PHOSPHOMOLYBDIC ACID AS A REOXIDANT IN THE PALLADIUM(II)-CATALYZED OXIDATION OF BUT-1-ENE TO BUTAN-2-ONE [J].

DAVISON, SF ;

MANN, BE ;

MAITLIS, PM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (06) :1223-1228

[10] INTERMEDIATE STEPS IN AUTOXIDATIONS .2. AUTOXIDATION AND ENOLIZATION OF ACETOPHENONE IN ACETIC ACID [J].

DENHERTOG, HJ ;

KOOYMAN, EC .

JOURNAL OF CATALYSIS, 1966, 6 (03) :357-+

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