OXIDATION OF 2-METHYLCYCLOHEXANONE AND CYCLOHEXANONE BY DIOXYGEN CATALYZED BY VANADIUM-CONTAINING HETEROPOLYANIONS

被引：57
作者：
ATLAMSANI, A
BREGEAULT, JM
ZIYAD, M
机构：
[1] UNIV PARIS 06,DEPT CHIM,CATALYSE & CHIM SURFACES LAB,CNRS,URA 1428,TOUR 54,BOITE 196,F-75252 PARIS 05,FRANCE
[2] UNIV MOHAMMED 5,FAC SCI,PHYSICOCHIM MAT & CATALYSE LAB,RABAT,MOROCCO
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 21期
关键词：
D O I：
10.1021/jo00073a026
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Methylcyclohexanone is oxidized by dioxygen in the presence of H3+n[PMo12-nVnO40].aq to give 6-oxoheptanoic acid. Solvent effects are studied. The same precursors with cyclohexanone in aqueous acetic acid give adipic acid as the major product and other dicarboxylic acids by oxidation of 6-oxohexanoic acid.
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页码：5663 / 5665
页数：3
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