FILLER ELASTOMER INTERACTIONS .9. PERFORMANCE OF SILICAS IN POLAR ELASTOMERS

被引：68
作者：
TAN, EH
WOLFF, S
HADDEMAN, M
GREWATTA, HP
WANG, MJ
机构：
[1] Degussa AG., Hurth
来源：
RUBBER CHEMISTRY AND TECHNOLOGY | 1993年 / 66卷 / 04期
关键词：
D O I：
10.5254/1.3538332
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Inverse gas-solid chromatography of silicas showed that the free energies of adsorption of polar probes were much higher than those obtained with n-alkanes. This implies that polymer-silica interaction is more pronounced in polar rubbers than in nonpolar rubbers such as polybutadiene. Using a series of silica and carbon-black-loaded acrylonitrile-butadiene (NBR) compounds with different acrylonitrile (ACN) content, this paper shows the changes in viscoelastic properties of the silica compounds can be attributed to improved polymer-filler interactions relative to the interactions involved in carbon-black compounds.
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页码：594 / 604
页数：11
相关论文
共 13 条
[1]  
HUMMEL K, 1962, KAUTSCH GUMMI KUNSTS, V15, P1
[2]  
Kraus G, 1963, J APPL POLYM SCI, V7, P861, DOI DOI 10.1002/APP.1963.070070306
[3]   BOUND RUBBER IN ELASTOMERS - ANALYSIS OF ELASTOMER-FILLER INTERACTION AND ITS EFFECT ON VISCOSITY AND MODULUS OF COMPOSITE SYSTEMS [J].
PLISKIN, I ;
TOKITA, N .
JOURNAL OF APPLIED POLYMER SCIENCE, 1972, 16 (02) :473-&
[4]  
RIGBI Z, 1968, RUBBER CHEM TECHNOL, V41, P752
[5]  
TAN EH, 1992, THESIS U HAUTE ALSAC
[6]   FILLER ELASTOMER INTERACTIONS .1. SILICA SURFACE ENERGIES AND INTERACTIONS WITH MODEL COMPOUNDS [J].
WANG, MJ ;
WOLFF, S ;
DONNET, JB .
RUBBER CHEMISTRY AND TECHNOLOGY, 1991, 64 (04) :559-576
[7]   FILLER ELASTOMER INTERACTIONS .3. CARBON-BLACK-SURFACE ENERGIES AND INTERACTIONS WITH ELASTOMER ANALOGS [J].
WANG, MJ ;
WOLFF, S ;
DONNET, JB .
RUBBER CHEMISTRY AND TECHNOLOGY, 1991, 64 (05) :714-736
[8]  
WANG MJ, 1992, KAUT GUMMI KUNSTST, V45, P11
[9]  
WANG MJ, 1992, MAY M RUBB DIV LOUIS
[10]   FILLER ELASTOMER INTERACTIONS .4. THE EFFECT OF THE SURFACE ENERGIES OF FILLERS ON ELASTOMER REINFORCEMENT [J].
WOLFF, S ;
WANG, MJ .
RUBBER CHEMISTRY AND TECHNOLOGY, 1992, 65 (02) :329-342
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