ELECTRON VIBRATION EFFECTS IN CS2GEF6-MN4+ USING 2-PHOTON ABSORPTION

被引：8

作者：

CAMPOCHIARO, C ^{[1
]}

FLINT, CD ^{[1
]}

HASAN, Z ^{[1
]}

HOLLINGSWORTH, G ^{[1
]}

MCCLURE, DS ^{[1
]}

机构：

[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544

来源：

JOURNAL OF LUMINESCENCE | 1994年 / 58卷 / 1-6期

关键词：

D O I：

10.1016/0022-2313(94)90348-4

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Consequences of electron vibration coupling have been investigated using one- and two-photon spectra of Mn4+ in cubic Cs2GeF6 and CS2SiF6. The observations clearly demonstrate a linear Jahn-Teller effect, a Ham effect in electronic and vibronic energy levels, and a quadratic Jahn-Teller or Satten effect.

引用

页码：1 / 4

页数：4

共 9 条

[1] SELECTIVE EXCITATION AND ANALYSIS OF NAF-CU+ ELECTRONIC-TRANSITIONS USING 2-COLOR, 2-PHOTON SPECTROSCOPY
BERG, JM
MCCLURE, DS
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[2] VIBRONIC COUPLING IN THE TWO-PHOTON 4A2-]4T2 SPECTRUM OF MN-4+ IN THE CUBIC AND TRIGONAL SITES OF CS2SIF6, CS2GE6, CS2TI6
CAMPOCHIARO, C
MCCLURE, DS
RABINOWITZ, P
DOUGAL, S
[J]. CHEMICAL PHYSICS LETTERS, 1989, 157 (1-2) : 78 - 82
[3] CAMPOCHIARO C, 1989, THESIS PRINCETON U
[4] HAM FS, 1965, PHYS REV A, V138, P1277
[5] HASAN Z, IN PRESS
[6] HASAN Z, 1979, THESIS AUSTR NATIONA
[7] JAHN-TELLER EFFECT IN THE 4T2G STATE OF MN4+ IN CS2SIF6
MANSON, NB
HASAN, Z
FLINT, CD
[J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1979, 12 (24): : 5483 - 5488
[8] SATTEN RA, 1971, PHYS REV A, V3, P1248
[9] Wyckoff R., 1965, CRYSTAL STRUCTURES, VI

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