SYNTHESIS OF CHIRAL N-PROTECTED ALPHA-AMINO-BETA-DIKETONES FROM ALPHA-DIAZOKETONES DERIVED FROM NATURAL AMINO-ACIDS

被引：78

作者：

YE, T ^{[1
]}

MCKERVEY, MA ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 37期

关键词：

D O I：

10.1016/S0040-4020(01)80473-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha-Diazoketols, prepared by condensation of aldehydes or ketones with lithiated optically active alpha-diazoketones derived from natural amino acids, rearrange to homochiral alpha-amino-beat-diketones on treatment with rhodium(II) acetate.

引用

页码：8007 / 8022

页数：16

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