THE STEREOSELECTIVE CONSTRUCTION OF (Z)-3-ARYL-2-FLUOROALKENOATES

被引：50
作者：
WELCH, JT
HERBERT, RW
机构：
[1] Department of Chemistry, University at Albany, State University of New York, Albany
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 16期
关键词：
D O I：
10.1021/jo00303a003
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
: The use of 2,4,6-trimethylphenyl a-silyl-a-fluoroacetate in the Peterson olefination reaction leads to the highly stereoselective formation of (Z)-3-aryl-2-fluoroalkenoates via an aldol reaction most likely proceeding through an open transition state since stereocon-trol of the enolate geometry was not possible. © 1990, American Chemical Society. All rights reserved.
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页码：4782 / 4784
页数：3
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