ABSORPTION OF ISOBUTYLENE IN AQUEOUS SOLUTIONS OF SULPHURIC ACID

被引:49
|
作者
GEHLAWAT, JK
SHARMA, MM
机构
[1] Department of Chemical Technology, University of Bombay, Bombay, 19, Matunga
关键词
D O I
10.1016/0009-2509(68)89024-4
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The kinetics of absorption of isobutylene in aqueous solutions of sulphuric acid in the range of concentrations of industrial importance was studied in a stirred cell and a jet apparatus. The pseudo-first order reaction rate constant at 30°C was found to vary from 56 sec-1 to 7·87 × 105 sec-1 over the sulphuric acid concentrations of 49·5 per cent (7·0 g mole/l.) to 71·0 per cent (11·75 g mole/l.). The apparent energy of activation was found to be 13·0 kcal/g mole. © 1968.
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页码:1173 / &
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