AN ASSESSMENT OF 2ND-HARMONIC GENERATION BY DONOR-ACCEPTOR MOLECULES CONTAINING STILBENYL OR DIARYLAZO BRIDGES BETWEEN FERROCENYL DONOR AND NITRO ACCEPTOR GROUPS

被引：95
作者：
COE, BJ
JONES, CJ
MCCLEVERTY, JA
BLOOR, D
CROSS, G
机构：
[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,ENGLAND
[2] UNIV DURHAM,DEPT PHYS,SCI LABS,APPL PHYS GRP,DURHAM DH1 3LE,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 02期
关键词：
FERROCENE; 2ND HARMONIC GENERATION; NONLINEAR OPTICS; DIARYLAZO; STILBENYL;
D O I：
10.1016/0022-328X(94)87278-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds [Fe(eta(5)-C5H5)(eta(5)-C5H4-Ar) (Ar = 4,4'-C6H4N2C6H4NO2 (1), 4,4'-C6H4N2C6H3(2'-Me)NO, (2), 4,4'-C6H3(3-Me)N2C6H3(2'-Me)NO2 (3) and trans-4,4'-C6H4(CH=CH)C6H4NO2 (4) have been synthesized and their second order non-linear optical properties assessed by use of the Kurtz powder test for second harmonic generation on irradiation at 1907 nm. The stilbenyl compound, 4, gave a signal of similar intensity to that of a urea standard but the others gave no detectable signal.
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页码：225 / 232
页数：8
相关论文
共 28 条
  • [1] 2ND-ORDER NONLINEAR OPTICAL-PROPERTIES OF DIIRONALKENYLIDYNE COMPLEXES - CRYSTAL-STRUCTURE OF ((ETA-C5H5)2FE2(CO)2(MU-CO)(MU-(E)-C-CH=CH-C6H4-(P)-NME2))+BF4-
    BANDY, JA
    BUNTING, HE
    GARCIA, MH
    GREEN, MLH
    MARDER, SR
    THOMPSON, ME
    BLOOR, D
    KOLINSKY, PV
    JONES, RJ
    PERRY, JW
    [J]. POLYHEDRON, 1992, 11 (12) : 1429 - 1435
  • [2] THE SYNTHESIS OF FERROCENYL COMPOUNDS WITH 2ND-ORDER OPTICAL NONLINEARITIES
    BUNTING, HE
    GREEN, MLH
    MARDER, SR
    THOMPSON, ME
    BLOOR, D
    KOLINSKY, PV
    JONES, RJ
    [J]. POLYHEDRON, 1992, 11 (12) : 1489 - 1499
  • [3] MOLECULAR 2ND-ORDER OPTICAL NONLINEARITIES OF METALLOCENES
    CALABRESE, JC
    CHENG, LT
    GREEN, JC
    MARDER, SR
    TAM, W
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) : 7227 - 7232
  • [4] Chemla D. S., 1987, NONLINEAR OPTICAL PR, V1
  • [5] Chemla D.S., 1987, NONLINEAR OPTICAL PR, V2
  • [6] QUADRATIC HYPERPOLARIZABILITIES OF SOME ORGANOMETALLIC COMPOUNDS
    CHENG, LT
    TAM, W
    MEREDITH, GR
    MARDER, SR
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 189 : 137 - 153
  • [7] SYNTHESIS AND STRUCTURE OF 4-FERROCENYL-2'-METHYL-4'-NITROAZOBENZENE
    COE, BJ
    FOULON, JD
    HAMOR, TA
    JONES, CJ
    MCCLEVERTY, JA
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 2032 - 2035
  • [8] 2ND HARMONIC-GENERATION BY BIMETALLIC COMPLEXES CONTAINING FERROCENYL AND MOLYBDENUM OR TUNGSTEN MONONITROSYL REDOX CENTERS
    COE, BJ
    JONES, CJ
    MCCLEVERTY, JA
    BLOOR, D
    KOLINSKY, PV
    JONES, RJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) : 1485 - 1487
  • [9] SYNTHESIS AND STRUCTURE OF (CIS)-[1-FERROCENYL-2-(4-NITROPHENYL)ETHYLENE], AN ORGANOTRANSITION METAL COMPOUND WITH A LARGE 2ND-ORDER OPTICAL NONLINEARITY
    GREEN, MLH
    MARDER, SR
    THOMPSON, ME
    BANDY, JA
    BLOOR, D
    KOLINSKY, PV
    JONES, RJ
    [J]. NATURE, 1987, 330 (6146) : 360 - 362
  • [10] HANN RA, 1989, ROYAL SOC CHEM SPECI, V69
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