2-[3-(Pyridin-1-ium-2-yl)-1H-pyrazol-1yl]-6-[3-(pyridin-2-yl)-1H-pyrazol-1-yl]pyridinium sulfate methanol monosolvate

被引：0

作者：

Huang, Linxia ^{[1
]}

Shu, Mouhai ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

single-crystal X-ray study; T = 293 K; mean sigma(C-C) = 0.005 angstrom; disorder in solvent or counterion; R factor = 0.053; wR factor = 0.163; data-to-parameter ratio = 12.6;

D O I：

10.1107/S1600536813008647

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title solvated salt, C21H17N7 2+·SO4 2-·CH3OH, was obtained when we attempted to prepare the complex of ferrous sulfate and 2,6-bis[3-(pyridin-2-yl)-1H-pyrazol-1-yl]pyridine in methanol. The dihedral angles between adjacent pyridine and pyrazole rings range from 3.8 (1) to 13.4 (1)°. An intramolecular N - H⋯N hydrogen bond occurs. In the crystal, N - H⋯O and O - H⋯N hydrogen bonds between solvent methanol molecules and the cations generate zigzag chains along [110].

引用

页码：O689 / +

页数：8

共 10 条

[1] Bruker, 2000, SMART SAINT
[2] A NEAR-PLANAR PENTADENTATE SILVER(I) COMPLEX - THE CRYSTAL AND MOLECULAR-STRUCTURE OF (2,2'-6',2'-6'',2'''-6''',2''''-QUINQUEPYRIDINE)SILVER(I) HEXAFLUOROPHOSPHATE
CONSTABLE, EC
DREW, MGB
FORSYTH, G
WARD, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) : 1450 - 1451
[3] Steric control of directional isomerism in dicopper(I) helicates of asymmetrically substituted 2,2':6',2'':2'',6'''-quaterpyridine derivatives
Constable, EC
Heirtzler, F
Neuburger, M
Zehnder, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (24) : 5606 - 5617
[4] OLIGOPYRIDINES AS HELICATING LIGANDS
CONSTABLE, EC
[J]. TETRAHEDRON, 1992, 48 (46) : 10013 - 10059
[5] The first example of a bis-monohelical complex: The crystal and molecular structure of [Mn-2(dmqpy)(2)(H2O)(2)(mu-Cl)][ClO4](3)center dot 4H(2)O (dmqpy=6,6''''-dimethyl-2,2':6',2'':6'',2''':6''''-quinquepyridine)
Fu, YJ
Li, Q
Zhou, ZY
Dai, WN
Wang, DF
Mak, TCW
Hu, HW
Tang, WX
[J]. CHEMICAL COMMUNICATIONS, 1996, (13) : 1549 - 1550
[6] Substituent-controlled assembly of helical complexes: Synthesis, crystal and molecular structures of double helical silver(I) complexes with substituted quinquepyridines
Fu, YJ
Sun, J
Li, Q
Chen, Y
Dai, WN
Wang, DF
Mak, TCW
Tang, WX
Hu, HW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (11): : 2309 - 2313
[7] 2,6-BIS(N-PYRAZOLYL)PYRIDINES - THE CONVENIENT SYNTHESIS OF A FAMILY OF PLANAR TRIDENTATE N3 LIGANDS THAT ARE TERPYRIDINE ANALOGS
JAMESON, DL
GOLDSBY, KA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (17) : 4992 - 4994
[8] Sheldrick G. M., 2003, SADABS
[9] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[10] publCIF: software for editing, validating and formatting crystallographic information files
Westrip, Simon P.
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 : 920 - 925

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