SILVER INTERCALATION IN JALPAITE - DETERMINATION OF THE CHEMICAL DIFFUSION-COEFFICIENT

被引:3
作者
SCHMIDT, JA [1 ]
SAGUA, AE [1 ]
机构
[1] UNIV NACL SUR,DEPT QUIM & INGN QUIM,FISICOQUIM INORGAN LAB,RA-8000 BAHIA BLANCA,ARGENTINA
关键词
INTERCALATION; JALPAITE; DIFFUSION COEFFICIENT; SILVER;
D O I
10.1016/0254-0584(96)80013-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The equilibrium zone adjacent to the ternary compound Jalpaite, in the phase diagram [(1-x-y)Ag + xCu + yS], was explored through a coulometric titration. Also, the chemical diffusion coefficient of silver in Jalpaite was determined as a function of the temperature by using the potentiometric method, and the results are expressed with the following equation: log (D) over tilde = 5.023455-5928.18(1/T).
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页码:253 / 257
页数:5
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