REACTIONS OF [(C(5)ME(5))ZRF3] WITH ALME(3) - SYNTHESIS AND STRUCTURE OF A ZIRCONIUM-ALUMINUM-CARBON CLUSTER

被引：54

作者：

HERZOG, A ^{[1
]}

ROESKY, HW ^{[1
]}

ZAK, Z ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199409671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transfer of methyl groups from 2 to 1 leads to the first Zr3Al6C7 cluster 3 [Eq. (a)], in which six metal atoms form an open cube shielded by Al and C atoms. The ZrAl distances in the cube are remarkably short. Zr/Al/C compounds are of interest with regard to Ziegler–Natta catalysts. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：967 / 968

页数：2

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