REACTIONS OF [(C(5)ME(5))ZRF3] WITH ALME(3) - SYNTHESIS AND STRUCTURE OF A ZIRCONIUM-ALUMINUM-CARBON CLUSTER

被引：54
|
作者：
HERZOG, A [1 ]
ROESKY, HW [1 ]
ZAK, Z [1 ]
NOLTEMEYER, M [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期
关键词：
D O I：
10.1002/anie.199409671
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transfer of methyl groups from 2 to 1 leads to the first Zr3Al6C7 cluster 3 [Eq. (a)], in which six metal atoms form an open cube shielded by Al and C atoms. The ZrAl distances in the cube are remarkably short. Zr/Al/C compounds are of interest with regard to Ziegler–Natta catalysts. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：967 / 968
页数：2
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