THERMOPHYSICAL PROPERTIES - WHAT HAVE WE LEARNED RECENTLY, AND WHAT DO WE STILL NEED TO KNOW

被引:8
作者
SANDLER, SI
机构
[1] Center for Molecular and Engineering Thermodynamics, Department of Chemical Engineering, University of Delaware, Newark, 19716, Delaware
关键词
DATA NEEDS; MODELS; MODELING NEEDS; PHASE BEHAVIOR; THERMODYNAMIC PROPERTIES; THERMOPHYSICAL PROPERTIES; TRANSPORT PROPERTIES;
D O I
10.1007/BF01458812
中图分类号
O414.1 [热力学];
学科分类号
摘要
Some recent developments in the areas of measurement, prediction, and correlation of thermophysical properties and phase behavior are reviewed. However, important problems remain, and some of these are not being addressed. Here a number of thermophysical properties problem areas are identified based on the prejudices of the author and a small survey of friends and colleagues in industry and academia. Many of the problems arise as result of changes in industrial emphasis, for example, from chemicals to materials and pharmaceuticals, changes in federal or local regulations permitting lower air and water emissions, changes in technology, and an interest in determining the fate of chemicals in the environment. Some of the research needs, both experimental and theoretical, to deal with these problems are discussed.
引用
收藏
页码:1013 / 1035
页数:23
相关论文
共 38 条
[1]  
Altgelt K. H., 1994, COMPOSITION ANAL HEA
[2]   EQUATION OF STATE FOR PURE SODIUM-CHLORIDE [J].
ANDERKO, A ;
PITZER, KS .
FLUID PHASE EQUILIBRIA, 1992, 79 :103-112
[3]   NEW REFERENCE EQUATION OF STATE FOR ASSOCIATING LIQUIDS [J].
CHAPMAN, WG ;
GUBBINS, KE ;
JACKSON, G ;
RADOSZ, M .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (08) :1709-1721
[4]   GLOBAL THERMODYNAMIC BEHAVIOR OF FLUIDS IN THE CRITICAL REGION [J].
CHEN, ZY ;
ABBACI, A ;
TANG, S ;
SENGERS, JV .
PHYSICAL REVIEW A, 1990, 42 (08) :4470-4484
[5]   HIGH-PRESSURE VAPOR-LIQUID-EQUILIBRIUM WITH A UNIFAC-BASED EQUATION OF STATE [J].
DAHL, S ;
MICHELSEN, ML .
AICHE JOURNAL, 1990, 36 (12) :1829-1836
[6]   THE MHV2 MODEL - A UNIFAC-BASED EQUATION OF STATE MODEL FOR PREDICTION OF GAS SOLUBILITY AND VAPOR-LIQUID-EQUILIBRIA AT LOW AND HIGH-PRESSURES [J].
DAHL, S ;
FREDENSLUND, A ;
RASMUSSEN, P .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (08) :1936-1945
[7]  
Fredenslund A, 1977, VAPOR LIQUID EQUILIB
[8]  
GMEHLING J, 1994, P INT S THERMODYNAMI, P60
[9]  
GMEHLING J, 1994, P INT S THERMODYNAMI, P283
[10]   VAPOR-LIQUID-EQUILIBRIA BY UNIFAC GROUP CONTRIBUTION .5. REVISION AND EXTENSION [J].
HANSEN, HK ;
RASMUSSEN, P ;
FREDENSLUND, A ;
SCHILLER, M ;
GMEHLING, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (10) :2352-2355