RUTHENIUM(IV) SILYL HYDRIDE COMPLEXES VIA REACTION OF SILANES WITH 16-ELECTRON [RU(ETA-5-C5ME5)(P(PR-I)3)X] (X = CL, CH2SIHPH2, SIMEPH2) COMPLEXES - HYDRIDE MIGRATIONS TO AN ETA-2-SILENE LIGAND

被引：49

作者：

CAMPION, BK ^{[1
]}

HEYN, RH ^{[1
]}

TILLEY, TD ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO, DEPT CHEM, 9500 GILMAN DR, LA JOLLA, CA 92093 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of [Ru(eta-5-C5Me5)(PPri3)(H)(eta-2-CH2=SiPh2)] with hydrosilanes occur via initial migration of hydride to the silene ligand, and eventually give disilyl hydride or silyl dihydride ruthenium(IV) complexes; the 16-electron chloride [Ru(eta-5-C5Me5)(PPri3)Cl] adds mesityl (Mes) silane to give [Ru(eta-5-C5Me5)(PPri3)(H)2(SiHClMes)] which was crystallographically characterized.

引用

页码：1201 / 1203

页数：3

共 7 条

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