REACTIONS OF TRIS(DIALKYLAMINO)PHOSPHINES WITH DIALKYLCHLORAMINES

被引：5

作者：

DENNEY, DB

FELTON, SM

机构：

[1] School of Chemistry, Rutgers, The State University, New Brunswick

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 01期

关键词：

D O I：

10.1021/ic50059a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(dialkylamino)phosphines react with dialkylchloramines to give tris(dialkylamino)chlorophosphonium chlorides, a Schiff base derived from the dialkylchloramine, and the parent amine. The reaction is thought to proceed by initial displacement on halogen to give a tris(dialkylammo)chlorophosphonium dialkylamide. This salt is in equilibrium with the starting materials. Reaction of the dialkylamide anion with dialkylchloramine yields the Schiff base and the parent amine. © 1968, American Chemical Society. All rights reserved.

引用

页码：99 / &

共 12 条

[1] THE CONVERSION OF PRIMARY AMINES TO CARBONYL COMPOUNDS BY A CHLOROMINE DEGRADATION [J].