ORIGIN OF THE DEACTIVATION OF A DEALUMINATED HY ZEOLITE DURING THE SYNTHESIS OF HYDROXYACETOPHENONES

被引：0

作者：

NEVES, I ^{[1
]}

MAGNOUX, P ^{[1
]}

GUISNET, M ^{[1
]}

机构：

[1] UNIV POITIERS,UFR SCI,CNRS,URA 350,CATALYSE CHIM ORGAN LAB,F-86022 POITIERS,FRANCE

来源：

BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE | 1995年 / 132卷 / 02期

关键词：

HY ZEOLITE; HYDROXYACETOPHENONE; COKE COMPOSITION; DEACTIVATION; ADSORPTION;

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Origin of the deactivation of a dealuminated HY zeolite during the synthesis of hydroxyacetophenones. Hydroxyacetophenones are produced from phenylacetate or equimolar mixtures of phenylacetate and water or phenol and acetic acid at 400 degrees C on a dealuminated HY zeolite (Si/Al = 15). This reaction is accompanied by the rapid formation of secondary heavy products. These products remain blocked in the zeolite pores because of their great polarity are responsible for the rapid deactivation of the zeolite. Adsorption of nitrogen or n-hexane on deactivated zeolites shows that the deactivation is essentially due to the blocking of the access to the active sites of reactants. However, the more pronounced deactivation that occurs when pure phenylacetate is used as reactant is due to the dehydroxylation of the zeolite with transformation of phenylacetate into phenol and acetic acid.

引用

页码：156 / 165

页数：10

共 19 条

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