SYNTHESIS AND CHARACTERIZATION OF CHLORO PYRAZOLATO BRIDGED BINUCLEAR ORGANOPLATINUM(II) COMPLEXES - SINGLE-CRYSTAL STRUCTURE OF [PT2PH2(MU-CL)(MU-PZ)(PME2PH)2]

被引：4

作者：

SINGHAL, A

JAIN, VK

PATEL, RP

VYAS, A

BOHRA, R

机构：

[1] BHABHA ATOM RES CTR,DIV CHEM,BOMBAY 400085,INDIA

[2] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 479卷 / 1-2期

关键词：

PLATINUM; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)84094-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chloro/pyrazolato-bridged binuclear organoplatinum(II) complexes of the type [Pt2Ar2(mu-Cl)(mu-NN)(PR3)2] (Ar = Ph or C6H4OMe-4; NNH = pyrazole (pzH), 3,5-dimethylpyrazole (dmpzH) or 3,4,5-tri-methylpyrazole (tmpzH); PR3 = PBu3, PMe2Ph or PMePh2) have been synthesized. These complexes exist exclusively in the cis form in which the phosphine ligands are trans to the bridging pyrazolate group. The crystal structure of [Pt2Ph2(mu-Cl)(mu-pz)(PMe2Ph)2] is reported.

引用

收藏

页码：87 / 91

页数：5

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