SYNTHESIS AND CHARACTERIZATION OF CHLORO PYRAZOLATO BRIDGED BINUCLEAR ORGANOPLATINUM(II) COMPLEXES - SINGLE-CRYSTAL STRUCTURE OF [PT2PH2(MU-CL)(MU-PZ)(PME2PH)2]

被引：4
作者：
SINGHAL, A
JAIN, VK
PATEL, RP
VYAS, A
BOHRA, R
机构：
[1] BHABHA ATOM RES CTR,DIV CHEM,BOMBAY 400085,INDIA
[2] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 479卷 / 1-2期
关键词：
PLATINUM; CRYSTAL STRUCTURE;
D O I：
10.1016/0022-328X(94)84094-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chloro/pyrazolato-bridged binuclear organoplatinum(II) complexes of the type [Pt2Ar2(mu-Cl)(mu-NN)(PR3)2] (Ar = Ph or C6H4OMe-4; NNH = pyrazole (pzH), 3,5-dimethylpyrazole (dmpzH) or 3,4,5-tri-methylpyrazole (tmpzH); PR3 = PBu3, PMe2Ph or PMePh2) have been synthesized. These complexes exist exclusively in the cis form in which the phosphine ligands are trans to the bridging pyrazolate group. The crystal structure of [Pt2Ph2(mu-Cl)(mu-pz)(PMe2Ph)2] is reported.
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收藏
页码：87 / 91
页数：5
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