FROM CRYSTAL TO CRYSTAL - A RECONSTRUCTIVE SOLID-STATE REACTION

被引：9

作者：

WAGNER, T ^{[1
]}

EIGENDORF, U ^{[1
]}

HERBERICH, GE ^{[1
]}

ENGLERT, U ^{[1
]}

机构：

[1] TH AACHEN,INST ANORGAN CHEM,PROF PIRLET STR 1,D-52074 AACHEN,GERMANY

来源：

STRUCTURAL CHEMISTRY | 1994年 / 5卷 / 04期

关键词：

SOLID-STATE REACTION; SINGLE-CRYSTAL REACTION; MOLECULAR PACKING; 2-CHLORO-2-BORAINDANE DIETHYLETHER; 2-CHLORO-2-BORAINDANE;

D O I：

10.1007/BF02275496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the Lewis acid-base adduct of 2-chloro-2-boraindane and diethylether was determined by X-ray diffraction. After abstraction of the boron-coordinated Et2O molecule in vacuo, the crystal and molecular structure of the solvent-free boraindane, earlier synthesized by Kaufmann and Schacht [1], was studied on the resulting crystalline material. The different crystal packing in both structures and a diffraction experiment on an oriented single crystal showed that the reaction is reconstructive and that a rearrangement of the molecules parallels the change in molecular geometry.

引用

页码：233 / 237

页数：5

共 32 条

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