FROM CRYSTAL TO CRYSTAL - A RECONSTRUCTIVE SOLID-STATE REACTION

被引：9

作者：

WAGNER, T ^{[1
]}

EIGENDORF, U ^{[1
]}

HERBERICH, GE ^{[1
]}

ENGLERT, U ^{[1
]}

机构：

[1] TH AACHEN,INST ANORGAN CHEM,PROF PIRLET STR 1,D-52074 AACHEN,GERMANY

来源：

STRUCTURAL CHEMISTRY | 1994年 / 5卷 / 04期

关键词：

SOLID-STATE REACTION; SINGLE-CRYSTAL REACTION; MOLECULAR PACKING; 2-CHLORO-2-BORAINDANE DIETHYLETHER; 2-CHLORO-2-BORAINDANE;

D O I：

10.1007/BF02275496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the Lewis acid-base adduct of 2-chloro-2-boraindane and diethylether was determined by X-ray diffraction. After abstraction of the boron-coordinated Et2O molecule in vacuo, the crystal and molecular structure of the solvent-free boraindane, earlier synthesized by Kaufmann and Schacht [1], was studied on the resulting crystalline material. The different crystal packing in both structures and a diffraction experiment on an oriented single crystal showed that the reaction is reconstructive and that a rearrangement of the molecules parallels the change in molecular geometry.

引用

页码：233 / 237

页数：5

共 32 条

[1] THE REACTION OF (TRIFLUOROMETHYL)DIALKYLAMINOBORANES WITH HF, HCL AND HBR - X-RAY STRUCTURE INVESTIGATION OF THE AMINEBORANES (CF3)2B(F)NHME2 AND (CF3)2B(OH)NHME2 [J].

BRAUER, DJ ;

BURGER, H ;

PAWELKE, G ;

WEUTER, W ;

WILKE, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 329 (03) :293-304

[2] AM1 CALCULATIONS FOR COMPOUNDS CONTAINING BORON [J].

DEWAR, MJS ;

JIE, CX ;

ZOEBISCH, EG .

ORGANOMETALLICS, 1988, 7 (02) :513-521

[3] INDEXING IN SINGLE-CRYSTAL DIFFRACTOMETRY WITH AN OBSTINATE LIST OF REFLECTIONS [J].

DUISENBERG, AJM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1992, 25 :92-96

[4]

FRENZ BA, 1978, COMPUTING CRYSTALLOG

[5] THE CALCULATION OF MOLECULAR VOLUMES AND THE USE OF VOLUME ANALYSIS IN THE INVESTIGATION OF STRUCTURED MEDIA AND OF SOLID-STATE ORGANIC-REACTIVITY [J].

GAVEZZOTTI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) :5220-5225

[6] NITRITO-NITRO LINKAGE ISOMERIZATION IN THE SOLID-STATE .1. X-RAY CRYSTALLOGRAPHIC STUDIES OF TRANS-BIS(ETHYLENEDIAMINE)(ISOTHIOCYANATO)NITRITOCOBOLT(III) AND TRANS-BIS(ETHYLENEDIAMINE)(ISOTHIOCYANATO)NITROCOBALT(III) PERCHLORATE AND IODIDE [J].

GRENTHE, I ;

NORDIN, E .

INORGANIC CHEMISTRY, 1979, 18 (04) :1109-1116

[7] NITRITO-NITRO LINKAGE ISOMERIZATION IN THE SOLID-STATE .2. COMPARATIVE-STUDY OF THE STRUCTURES OF NITRITO-PENTAAMMINECOBALT(III) DICHLORIDE AND NITROPENTAAMMINECOBALT(III) DICHLORIDE [J].

GRENTHE, I ;

NORDIN, E .

INORGANIC CHEMISTRY, 1979, 18 (07) :1869-1874

[8]

HASEGAWA M, 1987, ORGANIC SOLID STATE

[9] 2-BORAINDANES AND 2-(DIALKYLAMINO)-2-BENZOBOROLE DIANIONS [J].

HERBERICH, GE ;

EIGENDORF, U ;

ENGLERT, U .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (06) :1397-1402

[10]

Johnson C.K., 1976, ORNL5138

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