Isopropyl 2,2-bis(4-bromophenyl)-2-hydroxyacetate

被引:0
作者
Smith, Graham [1 ]
机构
[1] Queensland Univ Technol, Fac Sci & Engn, GPO Box 2434, Brisbane, Qld 4001, Australia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金
澳大利亚研究理事会;
关键词
data-to-parameter ratio = 16.2; disorder in main residue; mean ω(C-C) = 0.010 Å; R factor = 0.055; single-crystal X-ray study; T = 200 K; wR factor = 0.156;
D O I
10.1107/S1600536812044571
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C17H16Br2O3, which is a restricted commercial acaricide (common name bromopropylate), has two independent and conformationally similar molecules in the asymmetric unit [dihedral angles between the planes of the two phenyl rings = 68.7 (4) and 77.4 (5)degrees]. The C atoms of the isopropyl group of one of the molecules are disordered over two sites with occupancies of 0.638 (16) and 0.362 (16). Minor non-merohedral twinning was also present in the crystal. Intermolecular O-H center dot center dot center dot O hydrogen-bonding interactions involving the hydroxy groups and carboxyl O-atom acceptors give separate centrosymmetric homodimers through cyclic hydrogen-bonding motifs [graph set R-2(2) (10)].
引用
收藏
页码:O3276 / +
页数:13
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