SYNTHESIS AND CHARACTERIZATION OF IRIDIUM CHLORIDE COMPLEXES .1. USE OF N-ALKYLPHENOTHIAZINE DRUGS AS LIGANDS

被引：10
|
作者：
GOWDA, NMM
KYI, MM
ZHANG, L
机构：
[1] Department of Chemistry, Western Illinois University, Macomb, 61455, IL
来源：
TRANSITION METAL CHEMISTRY | 1993年 / 18卷 / 05期
关键词：
D O I：
10.1007/BF00136618
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Iridium complexes of N-alkylphenothiazines have been prepared in MeOH. The polynuclear complexes obtained have been characterized by elemental analyses, magnetic susceptibilities, molar conductivities, thermogravimetric analysis and spectral data. The molecular formulae of the new complexes are as follows: [Ir3(LH)4Cl10]Cl2.xMeOH, where L = chlorpromazine (CP), promethazine (PM) or ethopropazine (EP), and x = 1 for CP and 2 for PM or EP; [Ir(TFH2)2Cl4] [IrCl6].MeOH, where TF = trifluoperazine; and [Ir3(TRH)2Cl11(MeOH)]Cl.MeOH and [Ir4(TRH)3Cl15], where TR = thioridazine. The complexes are diamagnetic in nature. Tentative structures are proposed for the complexes.
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页码：518 / 522
页数：5
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