STRUCTURE AND THE THERMODYNAMICS OF NONELECTROLYTE MIXTURES

被引：114
作者：
PATTERSON, D
机构：
[1] Department of Chemistry, McGill University, Montreal, H3A 2K6, PQ
来源：
JOURNAL OF SOLUTION CHEMISTRY | 1994年 / 23卷 / 02期
关键词：
EXCESS THERMODYNAMIC QUANTITIES; HEAT CAPACITY; ORIENTATIONAL ORDER; CONCENTRATION FLUCTUATIONS; ALCOHOLS; HYDROPHOBIC HYDRATION;
D O I：
10.1007/BF00973540
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A review is given of thermodynamic effects arising from the following types of order in liquid components or their mixtures: quadrupolar order in benzene as shown by the benzene-cyclohexane system, orientational order in long-chain normal alkanes revealed by their mixtures with globular molecules, non-randomness in mixtures approaching phase separation, alcohol multimers in inert solvents, water-structuring around hydrophobic solutes, and micelles.
引用
收藏
页码：105 / 120
页数：16
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