STRUCTURAL SYSTEMATICS IN MOLECULAR INORGANIC-CHEMISTRY

被引：56

作者：

ORPEN, AG

机构：

[1] School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom

[2] University of Cape Town

[3] Cambridge University

[4] Brookhaven National Laboratory, United States

[5] University of Bristol

来源：

CHEMICAL SOCIETY REVIEWS | 1993年 / 22卷 / 03期

关键词：

D O I：

10.1039/cs9932200191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Applications of crystal structural data to molecular inorganic chemistry are described. The use of empirical correlations between structural parameters to provide insights into transition metal chemistry is illustrated. Examples are given of applications of this approach to determining typical molecular dimensions. testing theories of bonding, exploring conformational behaviour of flexible species. and analysing reaction pathways. The relationship between the experimental observations and the theory used in their interpretation is discussed.

引用

页码：191 / 197

页数：7

共 37 条

[21] MOLECULAR-ORBITAL THEORY OF ELECTRONIC-STRUCTURE OF ORGANIC COMPOUNDS .23. PSEUDOROTATION IN SATURATED 5-MEMBERED RING COMPOUNDS [J].