DUAL REACTIVITY OF 2,3,5,6-TETRABROMO-4-METHYL-4-NITROCYCLOHEXA-2,5-DIENONE

被引：3

作者：

COOMBES, RG ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 07期

关键词：

D O I：

10.1039/p29920001007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,3,5,6-Tetrabromo-4-methyl-4-nitrocyclohexa-2,5-dienone in acetone solution nitrates 4-methoxyphenol by a radical mechanism, but acts mainly as a brominating agent towards phenol, after rearrangement.

引用

页码：1007 / 1008

页数：2

共 7 条

[1] CALO V, 1971, CHIM IND-MILAN, V53, P467
[2] THE MECHANISM OF NITRATION BY 4-METHYL-4-NITRO-2,3,5,6-TETRABROMOCYCLOHEXA-2,5-DIENONE
COOMBES, RG
RIDD, JH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (02) : 174 - 175
[3] GUY A, 1982, TETRAHEDRON, V38, P2339, DOI 10.1016/0040-4020(82)87011-7
[4] REGIOSPECIFIC CHLORINATION OF AROMATIC SUBSTRATES USING DONOR-ACCEPTOR AND HYDROGEN-BONDING INTERACTIONS
GUY, A
LEMAIRE, M
GUETTE, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (01) : 8 - 9
[5] SIMPLE RULES FOR CHEMICALLY INDUCED DYNAMIC NUCLEAR POLARIZATION
KAPTEIN, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (14): : 732 - &
[6] CHEMICALLY INDUCED DYNAMIC NUCLEAR POLARIZATION .8. SPIN DYNAMICS AND DIFFUSION OF RADICAL PAIRS
KAPTEIN, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (18) : 6251 - &
[7] NITROCYCLOHEXADIENONES - A NEW CLASS OF NITRATING AGENTS
LEMAIRE, M
GUY, A
ROUSSEL, J
GUETTE, JP
[J]. TETRAHEDRON, 1987, 43 (05) : 835 - 844

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