HYDROPHOBIC AND ANTIHYDROPHOBIC EFFECTS ON ORGANIC-REACTIONS IN AQUEOUS-SOLUTION

被引：0
|
作者：
BRESLOW, R
机构：
来源：
STRUCTURE AND REACTIVITY IN AQUEOUS SOLUTION: CHARACTERIZATION OF CHEMICAL AND BIOLOGICAL SYSTEMS | 1994年 / 568卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The presence of hydrophobic effects on solubilities, binding constants, and reaction rates and selectivities can be diagnosed, and made quantitative, by the use of prohydrophobic and antihydrophobic additives. Antihydrophobic agents act mainly by bridging between solutes and water, not by disrupting water structure. ''Water-like'' solvents are quite different from water in their behavior. Examples of observed hydrophobic effects include the Diels-Alder reaction, the benzoin condensation, binding to monomeric and dimeric cyclodextrins, and DNA stacking.
引用
收藏
页码：291 / 302
页数：12
相关论文
共 50 条
12345