INTERPRETATION OF ES, CS, AND IOS APPROXIMATIONS WITHIN A TRANSLATIONAL-INTERNAL COUPLING SCHEME .1. ATOM-DIATOM COLLISIONS

被引：34

作者：

COOMBE, DA

SNIDER, RF

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 11期

关键词：

D O I：

10.1063/1.438235

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rotational invariance is applied to the description of atom-diatom collisions in a translational-internal coupling scheme, to obtain energy sudden (ES), centrifugal sudden (CS), and infinite order sudden (IOS) approximations to the reduced scattering S matrix S(j̄λ̄;L;jλ). The method of presentation emphasizes that the translational-internal coupling scheme is actually the more natural description of collision processes in which one or more directions are assumed to be conserved. © 1979 American Institute of Physics.

引用

页码：4284 / 4296

页数：13

共 18 条

[1] THE THEORY OF SCATTERING BY A RIGID ROTATOR [J].