CHEMISTRY OF SILYLKETENE - A ONE-POT SYNTHESIS OF ALPHA-SILYL KETONES

被引：0
|
作者：
KITA, Y
MATSUDA, S
KITAGAKI, S
TSUZUKI, Y
AKAI, S
机构：
来源：
SYNLETT | 1991年 / 06期
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Addition of organocerium reagents 4 prepared from cerium(III) chloride and an alkyl- or aryllithium, to silylketenes 3a-c and the subsequent quenching with aqueous ammonium chloride or alkyl halides 5 gives the corresponding alpha-silyl ketones 1 in 53-99% yield.
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页码：401 / 402
页数：2
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