ELECTRON-BOMBARDMENT FOR DECAY OF CYCLOPENTADIENYLNITROSYLCHROMIUM COMPLEXES

被引：5

作者：

MULLER, J

LUDEMANN, F

SCHMITT, S

机构：

[1] Institut für Anorganische, Analytische Chemie der Technischen Universität berlin, D-1000 Berlin 12

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 169卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81452-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The low- and high-resolution mass spectra of CpCr(NO)2Cl (Cp = cyclopentadienyl) and of Cp2Cr2(NO)2(μ-NO)(μ-X) compounds with X = No, NH2, NHCH3, N(OH)-t-C4H9, N=CH2, and N=CH-n-C3H7 have been measured; complete fragmentation diagrams have been obtained by detection of metastable decompositions using a linked scan technique. The degradation of the dinuclear complexes is essentially determined by the bridging ligand X. The numerous rearrangements are partially characterized by transfer of the nitrosyl nitrogen onto other ligands with formation of CrO bonds. © 1979.

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页码：25 / 37

页数：13

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