CARBONYLPENTAAMMINERUTHENIUM(2) CHLORIDE . SYNTHESIS AND PROPERTIES

被引：32
作者：
STANKO, JA
STARINSH.TW
机构：
[1] Department of Chemistry, Pennsylvania State University, Pennsylvania 16802, University Park
来源：
INORGANIC CHEMISTRY | 1969年 / 8卷 / 10期
关键词：
D O I：
10.1021/ic50080a026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and isolation of the carbonylpentaamminemthenium(II) complex, Ru(NH3)5CO2+, as a chloride salt is described. The method of synthesis involved the ammination of the carbonyl halide anion, RuIICl4(H2O)CO2+ under mild conditions. A chemical and spectroscopic comparison of the carbon monoxide complex with the related molecular nitrogen complex is made, and the observed differences in the crystal structures and the infrared and electronic absorption spectra of the complexes are discussed. © 1969, American Chemical Society. All rights reserved.
引用
收藏
页码：2156 / &
相关论文
共 16 条
[1]   RUTHENIUM COMPLEXES CONTAINING MOLECULAR NITROGEN [J].
ALLEN, AD ;
BOTTOMLEY, F ;
HARRIS, RO ;
REINSALU, VP ;
SENOFF, CV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (22) :5595-+
[2]   NITROGENOPENTAMMINERUTHENIUM(2) COMPLEXES [J].
ALLEN, AD ;
SENOFF, CV .
CHEMICAL COMMUNICATIONS, 1965, (24) :621-&
[3]   MOLECULAR NITROGEN AS A LIGAND - CRYSTAL STRUCTURE OF NITROGENPENTAMMINERUTHENIUM(2) DICHLORIDE AND RELATED SALTS [J].
BOTTOMLEY, F ;
NYBURG, SC .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :1289-+
[4]   NATURE OF INTERMEDIATE GENERATED IN CATALYSED AQUATION OF SOME [COX(NH3)2]2+ IONS [J].
BUCKINGHAM, DA ;
OLSEN, II ;
SARGESON, AM .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1967, 20 (03) :597-+
[5]   STUDIES ON REACTION OF MOLECULAR NITROGEN WITH SOME TRANSITION METAL COMPLEXES [J].
CAMPBELL, CH ;
DIAS, AR ;
GREEN, MLH ;
SAITO, T ;
SWANWICK, MG .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 14 (02) :349-+
[6]   REDUCTION OF NITROGEN COMPLEXES [J].
CHATT, J ;
RICHARDS, RL ;
FERGUSSON, JE ;
LOVE, JL .
CHEMICAL COMMUNICATIONS, 1968, (23) :1522-+
[7]   FORMATION AND PROPERTIES OF SOME CHLORACARBONYL COMPLEXES OF RUTHENIUM (2) AND RUTHENIUM(3) [J].
HALPERN, J ;
JAMES, BR ;
KEMP, ALW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) :5142-&
[8]   FORMATION OF RU(NH3)5N22+ IN AQUEOUS SOLUTION BY DIRECT ACTION OF MOLECULAR NITROGEN [J].
HARRISON, DE ;
TAUBE, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (22) :5706-&
[9]   BINUCLEAR ION CONTAINING NITROGEN AS A BRIDGING GROUP [J].
HARRISON, DF ;
WEISSBERGER, E ;
TAUBE, H .
SCIENCE, 1968, 159 (3812) :320-+
[10]  
HERZBERG G, 1950, MOL SPECTRA MOL STRU, V1, P449
12