CARBONYLPENTAAMMINERUTHENIUM(2) CHLORIDE . SYNTHESIS AND PROPERTIES

被引：32

作者：

STANKO, JA

STARINSH.TW

机构：

[1] Department of Chemistry, Pennsylvania State University, Pennsylvania 16802, University Park

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 10期

关键词：

D O I：

10.1021/ic50080a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and isolation of the carbonylpentaamminemthenium(II) complex, Ru(NH3)5CO2+, as a chloride salt is described. The method of synthesis involved the ammination of the carbonyl halide anion, RuIICl4(H2O)CO2+ under mild conditions. A chemical and spectroscopic comparison of the carbon monoxide complex with the related molecular nitrogen complex is made, and the observed differences in the crystal structures and the infrared and electronic absorption spectra of the complexes are discussed. © 1969, American Chemical Society. All rights reserved.

引用

页码：2156 / &

共 16 条

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