OXYCHLORINATION OF ETHYLENE AT HIGH TEMPERATURES

被引：11
作者：
MAGISTRO.AJ
NICHOLAS, PP
CARROLL, RT
机构：
[1] B. F. Goodrich Research Center, Brecksville
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 02期
关键词：
D O I：
10.1021/jo01254a004
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The mechanism of ethylene oxychlorination to vinyl chloride (VCl) at 500-550° with an iron oxide containing catalyst has been established by deuterium labeling experiments. The data are consistent with a mechanism involving 1,2-dichloroethane (DCE) as the VCl precursor. The 2-chloroethyl radical or cation intermediate may directly contribute to VC1 formation if certain kinetic requirements are satisfied, but neither direct substitution on ethylene via a vinyl radical nor any mechanism involving ethyl chloride contributes significantly. © 1969, American Chemical Society. All rights reserved.
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页码：271 / &
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