CRYSTAL-STRUCTURE OF BASE-FREE [MOOI4](-)

被引：9

作者：

GORDON, JC

MATTAMANA, SP

POLI, R

FANWICK, PE

机构：

[1] UNIV MARYLAND,DEPT CHEM & BIOCHEM,COLLEGE PK,MD 20742

[2] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

POLYHEDRON | 1995年 / 14卷 / 10期

关键词：

D O I：

10.1016/0277-5387(94)00397-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Air oxidation of [PPh(4)](3)[Mo3I12] produces [PPh(4)][MoOI4], a rare example of an iodide-containing molybdenum(V) complex, whose structure has been determined by X-ray crystallography. This structural determination completes the [MoOX(4)](-) (X = Cl, Pr, I) series. The structural parameters are compared with those of the other halide analogues and with those of crystallographically characterized base adducts, [MoOI4(L)](-) (L = H2O, THF). Also, a comparison between the donor power of O2- vs the pentamethyl-cyclopentadienyl anion for molybdenum(V) is made possible by comparing [MoOI4](-) with the non-existent (eta-C(5)Me(5))MoI4.

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页码：1339 / 1342

页数：4

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