PRESSURE EFFECT ON THE ESTERIFICATION OF PHTHALIC-ANHYDRIDE IN SUPERCRITICAL CO2

被引：32
作者：
ELLINGTON, JB
BRENNECKE, JF
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期
关键词：
D O I：
10.1039/c39930001094
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Measurements of the bimolecular rate constants for the uncatalysed esterification of phthalic anhydride with methanol in supercritical CO2 indicate that the reaction rate is enhanced when operating in the compressible region due to increased local concentrations of the methanol around the phthalic anhydride.
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页码：1094 / 1095
页数：2
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