EPOXIDATION OF OLEFINS BY MOLECULAR-OXYGEN WITH CLAY-IMPREGNATED NICKEL-CATALYSTS

被引：41
作者：
BOUHLEL, E
LASZLO, P
LEVART, M
MONTAUFIER, MT
SINGH, GP
机构：
[1] ECOLE POLYTECH,CHIM FINE BIOMIMET & AUX INTERFACES LAB,F-91128 PALAISEAU,FRANCE
[2] FAC SCI MONASTIR,DEP CHIM,5019 MONASTIR,TUNISIA
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 07期
关键词：
HETEROGENEOUS CATALYSIS; AEROBIC OXIDATION; OXYGEN TRANSFER; MUKAIYAMA PROCEDURE;
D O I：
10.1016/S0040-4039(00)77506-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
With the supported ''clayniac'' catalyst, in the presence of i-butyraldehyde as a sacrificial reducer, olefins are epoxidized in good yields by compressed air at room temperature, in a convenient procedure.
引用
收藏
页码：1123 / 1126
页数：4
相关论文
共 25 条
[1]  
AUGUST PL, 1989, COMMUNICATION
[2]   CATION RADICAL CYCLO-ADDITIONS AND RELATED SIGMATROPIC REACTIONS [J].
BAULD, NL .
TETRAHEDRON, 1989, 45 (17) :5307-5363
[3]  
BLUCHER E, 1989, TECNOLOGIA ARGILAS
[4]  
BRILL WF, 1963, J ORG CHEM, V29, P7113
[5]   NICKEL(II) BROMIDE CATALYZED OXIDATIONS OF PRIMARY AND SECONDARY ALCOHOLS TO CARBONYL-COMPOUNDS BY BENZOYL PEROXIDE [J].
DOYLE, MP ;
PATRIE, WJ ;
WILLIAMS, SB .
JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (16) :2955-2956
[6]  
EMANUEL MN, 1984, OXIDATION ORGANIC CO, P46
[7]   IS A LINEAR RELATIONSHIP BETWEEN THE FREE-ENERGIES OF ACTIVATION AND ONE-ELECTRON OXIDATION POTENTIAL EVIDENCE FOR ONE-ELECTRON TRANSFER BEING RATE DETERMINING - INTERMEDIATES IN THE EPOXIDATION OF ALKENES BY CYTOCHROME-P-450 MODELS .4. EPOXIDATION OF A SERIES OF ALKENES BY OXO(MESO-TETRAKIS(2,6-DIBROMOPHENYL)PORPHINATO)-CHROMIUM(V)N [J].
GARRISON, JM ;
OSTOVIC, D ;
BRUICE, TC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4960-4966
[8]   EPOXIDATION REACTIONS CATALYZED BY IRON PORPHYRINS - OXYGEN-TRANSFER FROM IODOSYLBENZENE [J].
GROVES, JT ;
NEMO, TE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5786-5791
[9]   METAL-DEPENDENT REACTIVITY OF SOME METALLOPORPHYRINS IN OXIDATION WITH DIOXYGEN [J].
HABER, J ;
MLODNICKA, T ;
POLTOWICZ, J .
JOURNAL OF MOLECULAR CATALYSIS, 1989, 54 (03) :451-461
[10]  
HAINES A, 1985, METHODS OXIDATION OR
123