PREPARATION AND STRUCTURE OF TRICHLOROTRIS(DIMETHYLPHENYLPHOSPHINE)TUNGSTEN(III), THE 1ST STRUCTURALLY CHARACTERIZED NEUTRAL MONONUCLEAR COMPLEX OF TUNGSTEN(III)

被引：15

作者：

HILLS, A ^{[1
]}

HUGHES, DL ^{[1
]}

LEIGH, GJ ^{[1
]}

PRIETOALCON, R ^{[1
]}

机构：

[1] UNIV SUSSEX,INST PLANT SCI RES,AFRC,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 06期

关键词：

D O I：

10.1039/dt9910001515

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mononuclear complex of tungsten(III) has been obtained by the zinc reduction of [WCl4(PMe2Ph)3]. This product, [WCl3(PMe2Ph)3], has an octahedral, meridional configuration, and crystallises in the space group P2(1)/c, with a = 16.177(2), b = 10.350(1) and c = 18.079(2) angstrom, beta = 113.81(6)-degrees. It can be used to prepare other mononuclear tungsten(III) compounds. Its structural relationship with other complexes, [MCl3(PMe2Ph)3] (M = Re, Os or Ir), is discussed.

引用

页码：1515 / 1517

页数：3

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