Crystal structure of (4-fluorophenyl-kappa C-1)iodido(N,N,N',N-tetramethyl-ethylenediamine-kappa N-2,N')palladium(II)

被引:1
作者
Yan, Jin-Jin [1 ]
Zheng, Chang-Ge [1 ]
机构
[1] Jiangnan Univ, Sch Chem & Mat Engn, 1800 Lihu Rd, Wuxi 214122, Jiangsu, Peoples R China
关键词
crystal structure; palladium(II) complex; tetramethylethylenediamine; square-planar coordination; single-crystal X-ray study; hydrogen bonding;
D O I
10.1107/S2056989015008014
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Pd(C6H4F)I(C6H16N2)], the Pd-II atom is coordinated by two N atoms from the N,N,N',N'-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) angstrom. The angles about the Pdll atom range from 83.35 (16) to 178.59 (11)degrees. In the crystal, weak C-H center dot center dot center dot F and C-H center dot center dot center dot I hydrogen bonds link the molecules into sheets in the be plane.
引用
收藏
页码:M124 / U189
页数:9
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