INTERACTION OF COLORFORMERS AND COREACTANTS .2. CRYSTAL-STRUCTURE OF A XANTHENE TYPE COLORFORMER AND CADMIUM IODIDE

被引：13

作者：

RIHS, G ^{[1
]}

WEIS, CD ^{[1
]}

机构：

[1] UNIV S FLORIDA,DEPT CHEM,TAMPA,FL 33620

来源：

DYES AND PIGMENTS | 1991年 / 15卷 / 03期

关键词：

D O I：

10.1016/0143-7208(91)80001-P

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A crystalline adduct composed of a xanthene moiety representing the colorformer and cadmium iodide as the coreactant has been synthesized. Single crystals of the composition C56H46N2O6.Cd2I4.acetone were obtained as acetone solvate.13 C-NMR, X-ray and crystallographic data have been collected for this complex. Two xanthene parts are linked via their carboxylate groups to a four-membered ring composed of a Cd2I4 unit. Interatomic distances indicate that the molecule possesses a quinone-like structure, with the phenyl ring bearing the carboxylate group standing nearly at right angles to the xanthene part. Intercalated acetone molecules are a prerequisite for the formation of single crystals.

引用

页码：165 / 173

页数：9

共 8 条

[1] SYNTHESIS AND STRUCTURE OF [RHODAMINE-123]2PTCL4.4H2O - THE 1ST TETRACHLOROPLATINATE(II) SALT WITH ANTICANCER ACTIVITY [J].