SUBSTRATE-SPECIFICITY OF FLAX HYDROPEROXIDE ISOMERASE

被引：17

作者：

FENG, P

ZIMMERMAN, DC

机构：

[1] U.S. Dept. of Agriculture, Science and Education Administration, Agricultural Research, Department of Biochemistry, North Dakota State University, Fargo, 58105, North Dakota

来源：

LIPIDS | 1979年 / 14卷 / 08期

关键词：

D O I：

10.1007/BF02533895

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Incubations of the 13- and 9-hydroperoxides of linolenic acid with a flax acetone powder extract containing hydroperoxide isomerase resulted in the formation of 13-hydroxy-12-oxo-cis-9,15-octadecadienoic acid and 9-hydroxy-10-oxo-cis-12,15-octadecadienoic acid, respectively. The rate of formation of product from 13-hydroperoxy linolenic acid was 36 times that from 9-hydroperoxy linolenic acid. Analogous results were obtained with the 13- and 9-hydroperoxides of linoleic acid. The results demonstrated the substrate specificity of flax hydroperoxide isomerase. © 1979 American Oil Chemists' Society.

引用

页码：710 / 713

页数：4

共 16 条

[1]

Axelrod B., 1974, Advances in Chemistry Series, V136, P324

[2] DEGRADATION STUDIES ON PROSTAGLANDINS - PROSTAGLANDINS AND RELATED FACTORS 10 [J].

BERGSTROM, S ;

SJOVALL, J ;

RYHAGE, R ;

SAMUELSSON, B .

ACTA CHEMICA SCANDINAVICA, 1963, 17 (08) :2271-&

[3] SUBSTITUTION-REACTIONS OF LINOLEIC-ACID HYDROPEROXIDE ISOMERASE [J].

CHRISTIANSON, DD ;

GARDNER, HW .

LIPIDS, 1975, 10 (08) :448-453

[4] ANALYSIS OF AUTOXIDIZED FATS BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY - .1. METHYL OLEATE [J].

FRANKEL, EN ;

NEFF, WE ;

ROHWEDDER, WK ;

KHAMBAY, BPS ;

GARWOOD, RF ;

WEEDON, BCL .

LIPIDS, 1977, 12 (11) :901-907

[5] POSITIONAL SPECIFICITY OF GAMMA-KETOL FORMATION FROM LINOLEIC-ACID HYDROPEROXIDES BY A CORN GERM ENZYME [J].

GARDNER, HW ;

KLEIMAN, R ;

CHRISTIANSON, DD ;

WEISLEDER, D .

LIPIDS, 1975, 10 (10) :602-608

[6]

Graveland A., 1972, Technical Quarterly, Master Brewers Association of America, V9, P98

[7] ENZYMATIC OXIDATION OF LINOLENIC ACID IN AQUEOUS WHEAT-FLOUR SUSPENSIONS [J].

GRAVELAND, A .

LIPIDS, 1973, 8 (11) :606-611

[8]

MATTHEW JA, 1976, LIPIDS, V12, P324

[9]

NAKANISHI K, 1962, INFRARED ABSORPTION, P42

[10] RAPID, SENSITIVE, AND VERSATILE ASSAY FOR PROTEIN USING COOMASSIE BRILLIANT BLUE G250 [J].

SEDMAK, JJ ;

GROSSBERG, SE .

ANALYTICAL BIOCHEMISTRY, 1977, 79 (1-2) :544-552

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