GEOMETRY AND ELECTRONIC STRUCTURE OF SUBSTITUTED SCHIFFS BASES

被引：45

作者：

HOULDEN, SA

CSIZMADI.IG

机构：

[1] Department of Chemistry, Lash Miller Chemical Laboratories University of Toronto, Toronto 5, Ont.

来源：

TETRAHEDRON | 1969年 / 25卷 / 05期

关键词：

D O I：

10.1016/S0040-4020(01)82687-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One electron Extended Hückel Molecular Orbital (EHMO) theory has been used to study the conformational geometry of five benzal-p-X-aniline (X = H, Me3, Cl, Br, Me3O) Schiff's bases. The electronic structure predicted by this method was used as a guide for a least squares resolution of the observed electronic (UV) spectra. The resultant resolved spectra are discussed in terms of correlations of band shifts with substituent properties. © 1969.

引用

页码：1137 / &

共 43 条

[1] EXTENDED HUCKEL THEORY AND SHAPE OF MOLECULES
ALLEN, LC
RUSSELL, JD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (03) : 1029 - &
[2] PHOTOINDUCED ISOMERIZATIONS IN ANILS
ANDERSO.DG
WETTERMARK, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (07) : 1433 - +
[3] INTRAMOLECULAR HYDROGEN BONDING .2. THE DETERMINATION OF HAMMETT SIGMA-CONSTANTS BY INTRAMOLECULAR HYDROGEN BONDING IN SCHIFF BASES
BAKER, AW
SHULGIN, AT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (07) : 1523 - 1529
[4] The Electronic Structure of the Vanadyl Ion
Ballhausen, C. J.
Gray, Harry B.
[J]. INORGANIC CHEMISTRY, 1962, 1 (01) : 111 - 122
[5] BALLHAUSEN CJ, 1964, MOL ORBITAL THEORY, P122
[6] VALENCE ORBITAL IONIZATION POTENTIALS FROM ATOMIC SPECTRAL DATA
BASCH, H
VISTE, A
GRAY, HB
[J]. THEORETICA CHIMICA ACTA, 1965, 3 (05): : 458 - &
[7] BLOOR JE, 1960, CHEM IND-LONDON, P526
[8] BOWEN HJM, 1958, 11 CHEM SOC SPEC PUB
[9] BOWEN HJM, 1965, 18 CHEM SOC SPEC PUB
[10] ULTRA-VIOLET SPECTRA OF AZOMETHINES AND RELATED COMPOUNDS
BROCKLEHURST, P
[J]. TETRAHEDRON, 1962, 18 (MAR) : 299 - &

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