DEHYDRATION OF AMINES AND DIAMINES BY PERVAPORATION WITH IONOMER AND PVA-BASED MEMBRANES

被引:14
|
作者
XIE, HA [1 ]
NGUYEN, QT [1 ]
SCHAETZEL, P [1 ]
NEEL, J [1 ]
机构
[1] LCPM,CNRS,URA 494,1 RUE GRANDVILLE,BP 451,F-54001 NANCY,FRANCE
关键词
PERVAPORATION; DEHYDRATION; AMINES; IONOMER MEMBRANES; PVA-BASED MEMBRANES;
D O I
10.1016/0376-7388(93)85034-T
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Several ionomer membranes, GFT and over-crosslinked GFT hydrophilic membranes were studied in pervaporation of water-organic base [pyridine, dimethylisopropylamine (DMIPA), dimethyl propane diamine (DMPDA) and tetramethyl propane diamine (TMPDA) ] mixtures. Over-crosslinked GFT membranes showed the best selectivity in all cases with rather low fluxes. RAI 1010 (polystyrenesulfonic grafted onto Teflon) membranes generally exhibited the best overall performances. The selectivity of a given membrane for the studied amine decreases in the following order DMIPA > pyridine > DMPDA.
引用
收藏
页码:97 / 108
页数:12
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