PREPARATION AND STRUCTURAL CHARACTERIZATION OF CATIONIC DINUCLEAR RUTHENIUM(II) - THIOLATE COMPLEXES, [RU2(SPH)3(ETA-6-PARA-CYMENE)2]Y (Y=CL AND PF6)

被引：30

作者：

MASHIMA, K ^{[1
]}

MIKAMI, A ^{[1
]}

NAKAMURA, A ^{[1
]}

机构：

[1] OSAKA UNIV, FAC SCI, DEPT MACROMOLEC SCI, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 09期

关键词：

D O I：

10.1246/cl.1992.1795

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [RuCl2(p-cymene)]2 with sodium benzenethiolate in methanol afforded a cationic dinuclear ruthenium thiolate complexes, [Ru2(SPh)3(P-cymene)2]Y (2a Y = Cl; 2b: Y = PF6), whose structure is determined by X-ray analysis of 2b.

引用

页码：1795 / 1798

页数：4

共 50 条

[41] REACTIONS OF ALKENYL AND ALKYNYL RUTHENIUM(II) COMPLEXES WITH ISOCYANIDES - SYNTHESIS OF ALPHA-BETA-UNSATURATED ETA-ACYLRUTHENIUM(II) COMPLEXES AND X-RAY STRUCTURE OF [RU(CCPH)(CNTBU)3(PPH3)2]PF6
MONTOYA, J
SANTOS, A
LOPEZ, J
ECHAVARREN, AM
ROS, J
ROMERO, A
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 426 (03) : 383 - 398
[42] Synthesis and characterization of Ru(II) arene complexes, [Ru(η6-arene)(dppm)H]+ (η6-arene=benzene, p-cymene or hexamethylbenzene), [Ru(η6-arene)(py)3]2+ and [Ru(η6-arene)(py)2Cl]+
Sisodiya, OS
Sahay, AN
Pandey, DS
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2000, 39 (04): : 453 - 456
[43] Synthesis and reactivity of [Ru(Cp*)(L)(MeCN)2][PF6] (L = Ph2POMe or Ph2P-o-tolyl) and {Ru(Cp*)[Ph2PCH2C(tBu)=O](MeCN)}[PF6] complexes, their involvement as catalyst precursors for regioselective allylic substitution reactions and related [Ru(Cp*)Cl(Ph2POMe)(RCHCHCH2)][PF6] η3-allyl ruthenium(IV) intermediates
Demerseman, B
Renaud, JL
Toupet, L
Hubert, C
Bruneau, C
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (07) : 1371 - 1380
[44] Synthesis and reactions of coordinatively unsaturated 16-electron chalcogenolate complexes, Ru(EAr)2(η6-arene) and cationic binuclear chalcogenolate complexes, [(η6-arene)Ru(μ-EPh)3Ru(η6-arene)]PF6
Mashima, K
Kaneko, S
Tani, K
Kaneyoshi, H
Nakamura, A
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 545 : 345 - 356
[45] Preparation of a dicationic, p-cymene ruthenium(II) dimer, [(p-cymene)Ru(μ-Cl)(P{OCH2}3CEt)]2 2+: structure, characterization and reactivity
Bazemore, Joseph G.
Padgett, Clifford W.
Quillian, Brandon
JOURNAL OF COORDINATION CHEMISTRY, 2021, 74 (1-3) : 306 - 314
[46] Spectroscopic, luminescence and electrochemical studies on a pair of isomeric complexes [(bipy)2Ru(AB)PtCl2] [PF6]2 and [Cl2Pt(AB)Ru(bipy)2] [PF6]2, where AB is the bis-bipyridyl bridging ligand 2,2′:3′,2":6",2′′′-quaterpyridine
Barthram, AM
Ward, MD
Gessi, A
Armaroli, N
Flamigni, L
Barigelletti, F
NEW JOURNAL OF CHEMISTRY, 1998, 22 (08) : 913 - 917
[47] Synthesis, characterization, and reactivity of [Ru(bpy)(CH3CN)3(NO2)]PF6, a Synthon for [Ru(bpy)(L3)NO2] complexes
Freedman, Daniel A.
Kruger, Seth
Roosa, Christina
Wymer, Chandra
INORGANIC CHEMISTRY, 2006, 45 (23) : 9558 - 9568
[48] SYNTHESES AND PROPERTIES OF RUTHENIUM(II) COMPLEXES WITH OMICRON-QUINODIIMINE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF RU(BPY)2(C6H4(NH)2)(PF6)2
BELSER, P
VONZELEWSKY, A
ZEHNDER, M
INORGANIC CHEMISTRY, 1981, 20 (09) : 3098 - 3103
[49] Ruthenium(II) thiacrown complexes: Synthetic, spectroscopic, electrochemical, DFT, and single crystal X-ray structural studies of [Ru([15]aneS5)Cl](PF6)
Janzen, Daron E.
VanDerveer, Donald G.
Mehne, Larry F.
Grant, Gregory J.
INORGANICA CHIMICA ACTA, 2010, 364 (01) : 55 - 60
[50] (ETA-6-CYCLO-OCTA-1,3,5-TRIENE)(ETA-4-CYCLO-OCTA-1,5-DIENE) RUTHENIUM CHEMISTRY - PREPARATION OF [RU(ETA-6-ARENE)(ETA-5-CYCLO-OCTADIENYL)]PF6 COMPLEXES BY PROTONATION IN THE PRESENCE OF ARENES
VITULLI, G
PERTICI, P
BIGELLI, C
GAZZETTA CHIMICA ITALIANA, 1985, 115 (01): : 79 - 80

← 1 2 3 4 5 →