Crystal structure of [Ag(NH3)(3)](2)[Ag(NH3)(2)](2)[SnF6]F-2, a compound showing argentophilic interactions

被引：0
|
作者：
Kraus, Florian [1 ]
Fichtl, Matthias [1 ]
Baer, Sebastian [1 ]
机构：
[1] Philipps Univ Marburg, Anorgan Chem, Fluorchem, Fachbereich Chem, Hans Meerwein Str 4, D-35032 Marburg, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
关键词：
crystal structure; silver; argentophilic interactions; fluorides; ammine ligand;
D O I：
10.1107/S2056989016019010
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Bis[triamminesilver(I)] bis[diamminesilver(I)] hexafluoridostannate(IV) difluoride, [Ag(NH3)(3)](2)[Ag(NH3)(2)](2)[SnF6]F-2, was obtained in the form of colourless crystals from the reaction of CsAgSnF7 in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag center dot center dot center dot Ag distances in the range of argentophilic interactions. In the crystal, several N-H center dot center dot center dot F hydrogen bonds are present between the complex cations and the SbF6- and F- anions, leading to the formation of a three-dimensional network.
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页码：1860 / +
页数：8
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