LEWIS BASE-INDUCED REARRANGEMENT OF PRIMARY ETHYN-1-YLPHOSPHINES, A NEW AND EFFICIENT ROUTE TO PHOSPHAALKYNES

被引：37

作者：

GUILLEMIN, JC

JANATI, T

DENIS, JM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 05期

关键词：

D O I：

10.1039/c39920000415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphaalkynes bearing primary carbon substituents are prepared in good yield by low-temperature Lewis base-induced rearrangement of primary ethyn-1-ylphosphines; the mechanism involves a P-unsubstituted phosphaallene intermediate.

引用

页码：415 / 416

页数：2

共 21 条

[1] PHOSPHA-ALKENES AND PHOSPHA-ALKYNES, GENESIS AND PROPERTIES OF THE (P-P)PI-MULTIPLE BOND
APPEL, R
KNOLL, F
RUPPERT, I
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (09): : 731 - 744
[2] ACYLIDENPHOSPHINES AND ALKYLIDENEPHOSPHINES .15. 2,2-DIMETHYLPROPYLIDYNEPHOSPHINE, A STABLE COMPOUND WITH A PHOSPHORUS ATOM OF COORDINATION NUMBER-1
BECKER, G
GRESSER, G
UHL, W
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1981, 36 (01): : 16 - 19
[3] SPIROPENTADIENE
BILLUPS, WE
HALEY, MM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) : 5084 - 5085
[4] PHENYLYNOL AND MESITYLYNOL - THE 1ST GENERATION AND DIRECT OBSERVATION OF HYDROXYACETYLENES IN SOLUTION
CHIANG, Y
KRESGE, AJ
HOCHSTRASSER, R
WIRZ, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) : 2355 - 2357
[5] A CONVENIENT SYNTHESIS OF C-UNSUBSTITUTED AND C-MONOALKYLATED KETENE IMINES BY DEHYDROCYANATION OF IMIDOYL CYANIDES USING VACUUM GAS-SOLID REACTIONS
DECORTE, B
DENIS, JM
DEKIMPE, N
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (06) : 1147 - 1149
[6] SYNTHESIS OF NONSTABILIZED PHOSPHAALKYNES BY VACUUM GAS-SOLID HCL ELIMINATION
GUILLEMIN, JC
JANATI, T
GUENOT, P
SAVIGNAC, P
DENIS, JM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (02): : 196 - 198
[7] SYNTHESIS OF UNSTABILIZED LINEAR IMINES BY VACUUM GAS-SOLID REACTIONS
GUILLEMIN, JC
DENIS, JM
[J]. TETRAHEDRON, 1988, 44 (14) : 4431 - 4446
[8] PRIMARY ALKYNYLPHOSPHINES AND ALLENYLPHOSPHINES
GUILLEMIN, JC
SAVIGNAC, P
DENIS, JM
[J]. INORGANIC CHEMISTRY, 1991, 30 (09) : 2170 - 2173
[9] SUBSTITUENT EFFECTS ON NEUTRAL AND IONIZED-C=C AND C=O DOUBLE-BONDS AND THEIR IMPLICATIONS FOR THE STABILITY ORDER OF KETO ENOL TAUTOMERS
HEINRICH, N
KOCH, W
FRENKING, G
SCHWARZ, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (04) : 593 - 600
[10] FLASH PHOTOLYTIC GENERATION AND STUDY OF REACTIVE SPECIES - FROM ENOLS TO YNOLS
KRESGE, AJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (02) : 43 - 48

← 1 2 3 →