ON THE MECHANISM OF CARBON-HYDROGEN ACTIVATION IN GIF-TYPE REACTIONS - KINETIC ISOTOPIC EFFECTS IN PYRIDINE SOLUTION

被引：0
作者：
BARTON, DHR
DOLLER, D
GELETII, YV
机构：
[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843
[2] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 31期
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D O I：
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Kinetic isotopic effects (KIE) were measured for oxidation, bromination and selenylation of c-C6H12/c-C6D12 in pyridine solution for different Gif-type, Fenton and other systems. The comparison of KIE and relative reactivity data for the pair c-C5H10/c-C6H12 proved that the mechanism of activation in Gif-type reactions is different from a hydrogen atom abstraction.
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页码：3811 / 3814
页数：4
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