CLAY-CATALYZED ASYMMETRIC DIELS-ALDER REACTION OF CYCLOPENTADIENE WITH (-)-MENTHYL ACRYLATE

被引：24

作者：

CATIVIELA, C ^{[1
]}

FIGUERAS, F ^{[1
]}

FRAILE, JM ^{[1
]}

GARCIA, JI ^{[1
]}

MAYORAL, JA ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,CNRS,URA 418,CHIM ORGAN PHYS & CINET LAB,F-34053 MONTPELLIER 1,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(00)86134-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zn(II)-exchanged K10 montmorillonite is shown to be an efficient catalyst for the reaction between cyclopentadiene and (-)-menthyl acrylate, leading to the 1R,2R-cycloadduct with good chemical yield, high % d.e. and excellent endo/exo selectivity.

引用

页码：953 / 956

页数：4

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