SYNTHESIS AND CHARACTERIZATION OF SOME 1,4,8,11,15,18,22,25-OCTA-ALKYL-22,25-BIS(CARBOXYPROPYL)PHTHALOCYANINES AND 1,4,8,11,15,18-HEXA-ALKYL-22,25-BIS(CARBOXYPROPYL)PHTHALOCYANINES

被引：149

作者：

MCKEOWN, NB ^{[1
]}

CHAMBRIER, I ^{[1
]}

COOK, MJ ^{[1
]}

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 04期

关键词：

D O I：

10.1039/p19900001169

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of 3,6-dialkylphthalonitriles and 3,6-bis(4,4,4-trimethoxybutyl) phthalonitrite have been prepared via Diels-Alder reactions of 2,5-disubstituted furans or thiophene 1,1-dioxides with fumaro-nitrile. The phthalonitriles were converted into the title phthalocyanines as metal-free and copper(II) derivatives. The macrocycles were characterised using 1H NMR and optical spectroscopy, and fast-atom bombardment mass spectrometry. Certain examples exhibit discotic liquid crystal behaviour.

引用

页码：1169 / 1177

页数：9

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